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Water is a weak base in ethanol (pKA = 03) Liquid ammonia Self-ionization occurs according to the equation 2NH3* NH4+ + NH2~ and the pH range at -60 C is 32 units Acids that are weak in water, such as acetic acid, are strong in ammonia and acids that are very weak in water become medium strong in ammonia Strong bases include potassium amide, introducing NH2~ ions, while hydroxides are weak bases (a KOH solution with a concentration of 10~2 mol dm"3 has a pHNH3 value of about 245) If an amphiprotic solvent contains an acid and base that are neither mutually conjugate nor are conjugated with the solvent, a protolytic reaction occurs between these dissolved components Four possible situations can arise If both the acid and base are strong, then neutralization occurs between the lyonium ions and the lyate ions.

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0.5 1.0

If the acid is weak and the base strong, the acid reacts with the lyate ions produced by the strong base The opposite case is analogous A weak acid and a weak base exchange protons: Strong acid + strong base Weak acid + strong base Strong acid + weak base Weak acid 4- weak base.

1.5 m

5

(I) HA + S "->i\ " + HS (II) + H 2 S + + B ^ 1^B + HS (HI) HA + B- ]HB+ + A " (IV) (1.4.19)

Figure 9.3. Formation of SRG on an azopolymer, as generated by two-beam interference irradiation. The grating pitch, Lgr is determined by the wavelength and the incident angle of the irradiated light. The gure on the right exhibits a topographical image as measured by AFM.

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(Except for the last, these reactions are used in titrimetric neutralization analysis.) Reactions (II) to (IV) can also proceed in the opposite direction. This will be demonstrated on the well-known example of salt hydrolysis. Reaction (II) could be the neutralization of acetic acid by potassium hydroxide, yielding potassium acetate which can be isolated in the crystalline state. On dissolution in water the K+ cation is only hydrated in solution but does not participate in a protolytic reaction. In this way, the weak base CH3COO~ is quantitatively introduced into solution in the absence of an equilibrium amount of the conjugate weak acid CH3COOH. Thus

The keyboard, monitor, and mouse remain at the user s location/workplace, and communicate to the PC blade via a KVM interface device, which enables the remoting of the KVM functions between the PC blade and the user location. The interface device may be attached to the PC blade locally, or connected remotely over IP. Figure 5.3 shows how these components operate together. In both of these cases (remote and local), there is a 1 to 1 ratio one PC blade to one user.

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have been demonstrated in addition to SRG (Fukuda et al., 2001; Ye et al., 2001). The surface deformation mechanism needs to be understood by considering not only photochemical phenomena involving the azobenzene moiety and the mobility of the polymer matrix but also by interactions of the irradiation light with electric elds. Therefore, a large number of researchers are making continued efforts to clarify the complex deformation mechanism (Barada et al., 2006; Barret et al., 1996; Kumar et al., 1998; Pedersen et al., 1998).

CH3COO~ reacts with water to form an equilibrium concentration of CH3COOH molecules, corresponding to the K'A value for acetic acid in water: CH3COO- + H2O < CH3COOH + OH" , [CH3COOH][OH-] _ K^ a2Hc (1.4.20) KH " [CH3COO-] ~ KA(CH3COOH) " 1 - aH (the degree of hydrolysis of the salt present at the concentration c is orH = [OH-]/c = [CH3COOH]/c, [CH3COO"]/c = 1 - aH.) Because of this hydrolysis reaction, the solution becomes alkaline. For small degrees of hydrolysis ( a r H l ) , (L4.21) The concentration of oxonium ions increases with increasing strength of the acid and the pH decreases. The case of the salt of a weak base and strong acid is treated in an analogous way. With decreasing strength of the base, the concentration of oxonium ions increases and the pH decreases. In the case of the salt of a weak acid and a weak base HAB, e.g. ammonium acetate, hydrolysis of both the ions occurs: 2HAB + 2H2O A + HA + BH + + B + H 3 O + + OH~ For a high degree of hydrolysis [HA] ~ c and [B] ~ c, where c is the overall concentration of the salt. The electroneutrality condition gives [A~] + [OH~] = [H3O+] + [BH + ]. Here the concentrations [A"] and [BH+] are expressed by means of the acid dissociation constants KfA(HA) and K'A(BH+) and the oxonium concentration. Finally, we have

Remote, 1-1

[H3 ]=

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