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1.1.1 Terminology A substance present in solution or in a melt which is at least partly in the form of charged species ions is called an electrolyte. The decomposition of electroneutral molecules to form electrically charged ions is termed electrolytic dissociation. Ions with a positive charge are called cations; those with a negative charge are termed anions. Ions move in an electric field as a result of their charge cations towards the cathode, anions to the anode. The cathode is considered to be that electrode through which negative charge, i.e. electrons, enters a heterogeneous electrochemical system (electrolytic cell, galvanic cell). Electrons leave the system through the anode. Thus, in the presence of current flow, reduction always occurs at the cathode and oxidation at the anode. In the strictest sense, in the absence of current passage the concepts of anode and cathode lose their meaning. All these terms were introduced in the thirties of the last century by M. Faraday. R. Clausius (1857) demonstrated the presence of ions in solutions and verified the validity of Ohm's law down to very low voltages (by electrolysis 1

The sinusoidal light interference pattern at the sample surface leads to a sinusoidal surface patterning, that is, a surface relief grating (SRG) These gratings were found to be extremely large, up to hundreds of nanometers, as con rmed by atomic force microscopy (AFM) The SRGs diffract very ef ciently, and in retrospect, it is clear that many reports of large diffraction ef ciency before 1995, attributed to birefringence, were in fact due to surface gratings The process occurs readily at room temperature (well below the Tg of the amorphous polymers used) with moderate irradiation (1 100 mW cm 2) over seconds to minutes The phenomenon is a reversible mass transport, not irreversible material ablation, since a at lm with the original thickness is recovered upon heating above Tg Critically, it requires the presence and isomerization of azobenzene chromophores Other absorbing but nonisomerizing chromophores do not produce SRGs.

of a solution with direct current and unpolarizable electrodes) Up until that time, it was generally accepted that ions are formed only under the influence of an electric field leading to current flow through the solution The electrical conductivity of electrolyte solutions was measured at the very beginning of electrochemistry The resistance of a conductor R is the proportionality constant between the applied voltage U and the current / passing through the conductor It is thus the constant in the equation U = RI, known as Ohm's law The reciprocal of the resistance is termed the conductance The resistance and conductance depend on the material from which the conductor is made and also on the length L and cross-section S of the conductor If the resistance is recalculated to unit length and unit cross-section of the conductor, the quantity p = RS/L is obtained, termed the resistivity.

By creating flexible cloudlike infrastructures of hubs, bridges, switches, routers, gateways, and the functions these components provide, networks can be implemented using multiple technologies that meet varied informationflow requirements. Pathway virtualization creates the appearance of media to allow end nodes to communicate with each other regardless of the protocols and paths that may be used to move the data. For example, as discussed later, iSCSI encapsulates SCSI (small computer system interface) commands and data over an IP pathway, unbeknownst to the SCSI initiator and target. Likewise, an InfiniBand to Fibre Channel gateway allows a host to communicate via InfiniBand to native Fibre Channel storage devices. Pathway virtualization

Many other systems can exhibit optical surface patterning (Yamaki et al, 2000), but the amplitude of the modi cation is much smaller, does not involve mass transport, and usually requires additional processing steps The all-optical patterning unique to azobenzenes has been studied intensively since its discovery, yet there remains controversy regarding the mechanism The competing interpretations are evaluated in 4, where they are discussed at length Many reviews of the remarkable body of experimental results are available (Natansohn and Rochon, 2002; Delaire and Nakatani, 2000; Yager and Barrett, 2001; Viswanathan et al, 1999)..

For conductors consisting of a solid substance (metals, solid electrolytes) or single component liquids, this quantity is a characteristic of the particular substance In solutions, however, the resistivity and the conductivity K = l/p are also dependent on the electrolyte concentration c In fact, even the quantity obtained by recalculation of the conductivity to unit concentration, A = K/C, termed the molar conductivity, is not independent of the electrolyte concentration and is thus not a material constant, characterizing the given electrolyte Only the limiting value at very low concentrations, called the limiting molar conductivity A0, is such a quantity A study of the concentration dependence of the molar conductivity, carried out by a number of authors, primarily F W G Kohlrausch and W Ostwald, revealed that these dependences are of two types (see Fig 25) and thus, apparently, there are two types of electrolytes.

is supported in all of the network technologies used in blade environments, including Ethernet, Fibre Channel, and InfiniBand.

This work is dedicated to Professors Almeria Natansohn and Sukant Tripathy, teachers and pioneers in the eld of azo polymers, who were unable to see the completion of this book.