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Networks, because of their inherently redundant and flexible nature, are used in many different aspects of computing, including system-to-system communications, server-to-storage communications, and processor-to-processor communications.

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Free volume determination of azobenzene PMMA copolymer by a pulsed low energy positron lifetime beam with in situ UV illumination Macromolecules 37(21):8035 8042 Altomare A, et al 2001 Synthesis and polymerization of amphiphilic methacrylates containing permanent dipole azobenzene chromophores J Polym Sci, Part A 39(17):2957 2977 Altomare A, Ciardelli F, Tirelli N, Solaro R 1997 4 Vinylazobenzene: polymerizability and photochromic properties of its polymers Macromolecules 30(5):1298 1303 Anderle K, Birenheide R, Eich M, Wendorff JH 1989 Laser induced reorientation of the optical axis in liquid crystalline side chain polymers Makromol Chem, Rapid Commun 10(9):477 483 Anderle K, Birenheide R, Werner MJA, Wendorff JH 1991 Molecular addressing Studies on light induced reorientation in liquid crystalline side chain polymers Liq Cryst 9(5):691 699 Angeli C, Cimiraglia R, Hofmann H J 1996 On the competition between the inversion and rotation mechanisms in the cis trans thermal isomerization of diazene.

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called the electroneutrality condition, is valid on a macroscopic scale for every homogeneous part of the system but not for the boundary between two phases (see 4). From the physical point of view there cannot exist, under equilibrium conditions, a measurable excess of charge in the bulk of an electrolyte solution. By electrostatic repulsion this charge would be dragged to the phase boundary where it would be the source of a strong electric field in the vicinity of the phase. This point will be discussed in Section 3.1.3. In Eq. (1.1.1), as elsewhere below, z, is a dimensionless number (the charge of species i related to the charge of a proton, i.e. the charge number of the ion) with sign zt > 0 for cations and z, < 0 for anions. The electroneutrality condition decreases the number of independent variables in the system by one; these variables correspond to components whose concentration can be varied independently. In general, however, a number of further conditions must be maintained (e.g. stoichiometry and the dissociation equilibrium condition). In addition, because of the electroneutrality condition, the contributions of the anion and cation to a number of solution properties of the electrolyte cannot be separated (e.g. electrical conductivity, diffusion coefficient and decrease in vapour pressure) without assumptions about individual particles. Consequently, mean values have been defined for a number of cases. For example, the molality can be expressed for an electrolyte as a whole, mx\ the amount of substance ('number of moles') is expressed in moles of

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Chem Phys Lett 259(3 4):276 282 Angiolini L, Caretti D, Carlini C, Salatelli E 1995 Optically active polymers bearing side chain photochromic moieties: synthesis and chiroptical properties of methacrylic and acrylic homopolymers with pendant L lactic acid or L alanine residues connected to trans 4 aminoazobenzene Macromol Chem Phys 196(9):2737 2750 Antipov AA, Sukhorukov GB, Mohwald H 2003 In uence of the ionic strength on the polyelectrolyte multilayers permeability Langmuir 19(6):2444 2448 Anzai J I, Osa T 1994 Photosensitive arti cial membranes based on azobenzene and spirobenzopyran derivatives Tetrahedron 50(14):4039 4070 Aoki K, Nakagawa M, Ichimura K 2000 Self assembly of amphoteric azopyridine carboxylic acids: organized structures and macroscopic organized morphology in u enced by heat, pH change, and light J Am Chem Soc 122(44):10997 11004 Arai K, Kawabata Y 1995 Changes in the sol gel transformation behavior of azobenzene moiety containing methyl cellulose irradiated with UV light.

Local area networks (LANs), metropolitan area networks (MANs), and wide area networks (WANs) represent various levels of geographically distributed networks. (See Figure 6.1). A LAN enables multiple systems and storage to access each other over a smaller geography. This can be extended to larger geographies with the concept of virtual LANs (VLAN), using switches and connectivity over MANs and WANs. These traditional geographic boundaries blur when the same performance characteristics can be exhibited regardless of geography. MANs and WANs relate to larger and larger geography. However, in most cases the networks are all providing an appearance of media, which is a

formula units as if the electrolyte were not dissociated. For a strong electrolyte whose formula unit contains v+ cations and v_ anions, i.e. a total of v = v+ + v_ ions, the molalities of the ions are related to the total molality by a simple relationship, ra+ = v+ml and m_ = v_mY. The mean molality is then m = (ml+mv-)l/v = m , + v r - ) 1 / v (1.1.2)

Macromol Rapid Commun 16(12):875 880 Asakawa M, et al 1999 Photoactive azobenzene containing supramolecular complexes and related interlocked molecular compounds Chem Eur J 5(3):860 875..

The mean molality values m (moles per kilogram), mole fractions x (dimensionless number) and concentrations c (moles per cubic decimetre) are related by equations similar to those for non-electrolytes (see Appendix A). 1.1.3 Non-ideal behaviour of electrolyte solutions

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