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The Gibbs energy of an ion changes on transfer from one solvent to another primarily because the electrostatic interaction between ions and the medium changes as a result of the varying dielecric constant of the solvent. This can be expressed roughly by the Born equation (see Eq. 1.2.7), i _ i\

This section compares the photoinduced immobilization of IgG on two types of azopolymers (shown in Fig. 9.2) bearing various concentrations of 4-amino-4ucyanoazobenzene (CN-azopolymer) or amino azobenzene (H-azopolymer). CNazopolymer and H-azopolymer contain a push pull-type azobenzene and an amino azobenzene, respectively (Rabek, 1988). These azobenzenes have different

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Direct-attached storage (DAS) Application Network-attached storage (NAS) Application Storage area network (SAN) Application File System

(1A38)

1.5 Immuno chip ( g/mL)

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Mostly, Ds < D w so that the Gibbs energy increases on transfer from water to some other solvent. The determination of the standard Gibbs energies of transfer and their importance for potential differences at the boundary between two immiscible electrolyte solutions are described in Sections 3.2.7 and 3.2.8. 1.4.6 The acidity scale

1 ELISA ( g/mL)

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An exact description of the acidity of solutions and correlation of the acidity in various solvents is one of the most important problems in the theory of electrolyte solutions. In 1909, S. P. L. S0rensen suggested the logarithmic definition of acidity for aqueous solutions considering, at that time, of course, hydrogen instead of oxonium ions (cf. Eq. (1.4.11)) pH = -log a(H 3 O + ) = -log [H 3 O + ] - log y(H 3 O + ) (1.4.39)

A laptop computer with a serial ATA connection to an internal hard drive An Ethernet or USB cable to a connected storage device A server blade with an SAS or SATA drive on the blade itself

Figure 9.13. Correlation between the two methods, ELISA and immunochip, for quantifying mouse adiponectin at a level of 16 culture supernatant.

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This notional definition of the pH scale can, however, not be used for practical measurements, as it contains the activity coefficients of the individual ions, y(H 3 O + ). Under these conditions, an operational definition must be used, i.e. a definition based on the method by which the quantity pH is measured. Obviously, the operational definition must be formulated as closely as possible to the 'absolute' equation (1.4.39). In this way, a practical scale of pH is obtained that is very similar to the absolute scale but is not identical

adsorption spectra, and they exhibit different deformation and immobilization features under photoirradiation. Therefore, information can be obtained about the photoimmobilization mechanisms by comparing these two types of azopolymers. First, the authors examined the relationship between immobilization ef ciency and the indented depth with respect to the photoirradiation time and the speci c azobenzene moiety. Second, they compared the relationship between immobilization ef ciency and chemical structure, and elucidated how this correlated with the photoisomerization properties and the retention rate of immobilized antibodies. The photodeformation capabilities of the CN-azopolymer and the H-azopolymer were examined by determining the depth of the indents formed by polystyrene microspheres under LED irradiation. After photoirradiation and removal of the microspheres, regularly arranged indented patterns formed by the microspheres were observed on the surfaces of the azopolymers. The depths of the indents were plotted as a function of irradiation time for several kinds of azopolymers, as shown in Fig. 9.14. The indent depths in the azopolymer increased with increasing irradiation time. The depths of the indents saturated and reached a maximum after 30 min of photoirradiation for each of the azopolymers. The saturated depths were lowest in those azopolymers with the lowest content of azobenzene moieties. These results indicate that the photoresponsive moiety plays an important role in inducing photodeformation and that the indent depth is related to the content of the azobenzene in the azopolymers. There were no differences in photodeformation capabilities between the CN- and

20 Weight %H 2 S0 4 Fig. 1.11 Dissociation ranges of colour indicators for determination of the acidity function Ho in H2SO4-H2O mixtures: (1) p-nitroaniline, (2) o-nitroaniline, (3) p-chloro-o-nitroaniline, (4) /7-nitrodiphenylamine, (5) 2,4-dichloro-6-nitroaniline, (6) p-nitroazobenzene, (7) 2,6-dinitro-4methylaniline, (8) benzalacetophenone, (9) 6-bromo-2,4-dinitroaniline, (10) anthraquinone, (11) 2,4,6-trinitroaniline. (According to L. P. Hammett and A. J. Deyrup)

With NAS, the file system and storage components are distributed over a network infrastructure, enabling file sharing amongst multiple systems. NAS allows heterogeneous shared access to a common file system. In a blade environment, this NAS function is typically implemented outside the blade server system, with a network connection, usually GbE, between the blades and the NAS. With a SAN network, the file-system component remains in the server, and only the storage function is distributed over the network, enabling block-level access to storage devices over the network. The SAN enables access to a common set of storage space, configured into logical units of free space. Both GbE and FC are used for SAN networks.

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