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The conductivity of the membrane at the equilibrium potential (A0 = O), equal to the reciprocal of the polarization resistance value (Eq. 5.2.31), follows from Eqs (6.4.2), (6.4.3) and (4.3.5):

LIGHT-RESPONSIVE 2-D MOTIONS AND MANIPULATIONS IN AZOBENZENE-CONTAINING LIQUID CRYSTALLINE POLYMER MATERIALS

According to IDC, more than 500,000 blade units were shipped in 2005, representing 63% growth over 2004. Blade revenue generated in 2005 was $2.1 billion, representing 84% growth over 2004. Figure 3.3 shows the growth in the server blade installed base in the United States and worldwide. The growth rate of blades worldwide has been (and will probably continue to be) greater than the growth rate within the United States. One likely reason is that IT infrastructure outside the United States still lags, causing space and power availability to be even bigger issues outside the U.S. (particularly in places like India and China). Since blades offer significant advantages over rack servers in regard to these issues, their traction outside the United States is significant. In the fourth quarter of 2005, blade servers (including x86, EPIC, and RISC blades) accounted for 4.6% of total server market revenue. Figure 3.4 shows the growth in blade server shipments relative to total server shipments from 2002 2005.

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Research on azobenzene (Az)-containing polymeric lms has exploded during the past few decades, and it continues to be a very active area of materials chemistry (Ikeda et al., 2007; Seki, 2007, 2004; Ikeda, 2003; Natansohn and Rochon, 2002; Sekkat and Knoll, 2002; Ichimura, 2000; Irie, 2000; Kumar and Neckers, 1989). Azobenzene is perhaps the most frequently used photochromic unit to be incorporated in molecular assemblies and polymer liquid crystals (LCs). It has several advantageous features for fabrication of photoresponsive systems as follows. (i) Tedious synthesis is generally not required, leading to facile preparation of planned derivatives. (ii) The sensitivity of E (trans) form " Z (cis) photoisomerization is moderately high for both directions for derivatives having alkyl or alkoxyl substituents. Besides, less expensive light sources, such as a mercury lamp, can be used. (iii) Photofatigue is negligible under ordinary laboratory conditions. (iv) The molecular shape is rodlike and symmetric, which favors incorporation into various molecular assemblies, especially into liquid crystalline systems. The nal item is of particular importance to attain facile orientational controls and effectively induce motions. Thus far many efforts have been made to exert various types of performances in the liquid crystalline polymer

where ft = kjkd is the adsorption coefficient and c the bulk concentration of the ion. Equation (6.4.4) is valid when the coverage of the electrolyte-membrane interface is small. At higher concentrations of transferred ion, the ion transfer is retarded by adsorption on the opposite interface, so that the dependence of Go on c is characterized by a curve with a maximum, as has been demonstrated experimentally. Under certain conditions, the transfer of various molecules across the membrane is relatively easy. The membrane must contain a suitable 'transport mediator', and the process is then termed 'facilitated membrane transport'. Transport mediators permit the transported hydrophilic substance to overcome the hydrophobic regions in the membrane. For example, the transport of glucose into the red blood cells has an activation energy of only 16 kJ mol"1 close to simple diffusion. Either the transport mediators bind the transported substances into their interior in a manner preventing them from contact with the hydrophobic interior of the membrane or they modify the interior of the membrane so that it becomes accessible for the hydrophilic particles. A number of transport mediators are transport proteins; in the absence of an external energy supply, thermal motion leads to their conformational change or rotation so that the transported substance, bound at one side of the membrane, is transferred to the other side of the membrane. This type of mediator has a limited number of sites for binding the transported substance, so that an increase in the concentration of the latter leads to saturation. Here, the transport process is characterized by specificity for a given substance and inhibition by other transportable substances competing for binding sites and also by various inhibitors. When the concentrations of the transported substance are identical on both sides of the membrane,

3

Smart Light Responsive Materials. Edited by Yue Zhao and Tomiki Ikeda Copyright r 2009 John Wiley & Sons, Inc.