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Gomez-Lojero, The use of ionophores and channel formers in the study of the function of biological membranes, in Current Topics in Bioenergetics, Vol 6, p 221, Academic Press, New York, 1977 Gregoriadis, G (Ed), Liposome Technology, Vols 1-3, CRC Press, Boca Raton, 1984 Haydon, D A, and B S Hladky, Ion transport across thin lipid membranes: a critical discussion of mechanisms in selected systems, Quart Rev Biophys, 5, 187 (1972)..

Another example of azobenzene amphiphilic BCP whose hydrophilic block was prepared through two steps is also depicted in Fig 62 (structure c) (Qi et al, 2008), namely, quaternized poly(4-vinyl pyridine)-b-poly {6-[4-(4-ethoxyphenylazo)phenoxy]hexyl methacrylate} (QP4VP-b-PAzoMA) To obtain this BCP, chlorine-terminated poly(4-vinyl pyridine) (P4VP) was rst synthesized and then used to initiate the polymerization for PAzoMA The resulting diblock of P4VP-bPAzoMA was subjected to a quaternization reaction using bromoethane to obtain the amphiphilic BCP Other azobenzene amphiphilic BCPs prepared using ATRP whose hydrophilic block is not PEO were also reported (Ravi et al, 2005) We note that this chapter concerns only amphiphilic BCPs and does not cover the numerous works of azobenzene BCPs, including the early syntheses using other polymerization techniques, which was reviewed elsewhere (Zhao, 2007a).

Changes have also occurred in blade storage usage. Initially, when blade systems shipped, each blade contained some amount of disk storage. These first blade drives were all IDE (laptop-type) drives. The disks were very compact but had fairly high failure rates for hard-running servers. The next step for most vendors was to move to SCSI drives, as they got smaller (2.5-inch drives). This increased costs, but also reliability. As the market matured and blade usage expanded, a buzz started around a movement toward storage blades, which IBM delivered. Although storage blades were an interesting idea, they proved not to be flexible enough in a variety of ways for example, you could not simply pop out drives, which hindered serviceability, and difficulties in connecting server blades to storage blades required a different kind of routing. The general trend now has been to connect servers to storage through networked storage (NAS or SANs) for a number of reasons. First, networked storage offers high performance, high availability, and redundancy. Second, connecting to (and booting from) networked storage can eliminate the need for storage on the blade, allowing the blades to be more interchangeable. (This will be discussed in more detail in 7, Blades and Storage. )

Henderson, R, The purple membrane from Halobacterium halobium, Ann Rev Biophys Bioeng, 6, 87 (1977) Katchalsky, A, and P F Curran, Non-Equilibrium Thermodynamics in Biophysics, Harvard University Press, Cambridge, Mass, 1967 Knight, C G (Ed), Liposomes: From Physical Structure to Therapeutic Applications, Elsevier, North-Holland, Amsterdam, 1981 Kotyk, A, and K Janacek, Cell Membrane Transport, Principles and Techniques, 2nd ed, Plenum Press, New York, 1975 Lauger, P, Transport noise in membranes, Biochim Biophys Acta, 507, 337 (1978) Martonosi, A N (Ed), Membranes and Transport, Vols 1 and 2, Plenum Press, New York, 1982 Montal, M, and P Mueller, Formation of bimolecular membranes from iipid monolayers and a study of their electrical properties, Proc Natl Acad Sci USA, 69, 3561 (1972) Ovchinnikov, Yu A, V I Ivanov, and M M Shkrob, Membrane Active Complexones, Elsevier, Amsterdam, 1974 Papahadjopoulos, D (Ed.

It is of obvious interest to explore the use of other polymerization techniques that, being more tolerant to the experimental conditions and monomers, can produce amphiphilic azobenzene BCPs with no need for post reactions Notably, Su et al have recently reported the synthesis of such an amphiphilic diblock copolymer with PAA as the hydrophilic block using reversible addition fragmentation transfer (RAFT) polymerization (structure d in Fig 62) (Su et al, 2007) Using RAFT, they prepared PAA capped with dithiobenzoate and used it as the macro-RAFT transfer agent to polymerize the hydrophobic azobenzene polymer successfully It can be expected that more amphiphilic azobenzene BCPs will be synthesized using the controlled radical polymerization techniques (ATRP and RAFT) because of their simplicity, versatility, and ef ciency..

), Liposomes and Their Use in Biology and Medicine, Annals of the New York Academy of Science, Vol 308, New York, 1978 Pullmann, A (Ed), Transport Through Membranes: Carriers, Channels and Pumps, Kluwer, Dordrecht, 1988 Singer, S I, and G L Nicholson, The fluid mosaic model of the structure of cell membranes, Science, 175, 720 (1977) Skou, J C , J G Norby, A B Maunsbach and M Esmann (Eds), The Na+, K+-Pump, Part A, A R Liss, New York, 1988 Spack, G (Ed), Physical Chemistry of Transmembrane Motions, Elsevier, Amsterdam, 1983 Stryer, L, Biochemistry, W H Freeman & Co, New York, 1984 Ti Tien, H, Bilayer Lipid Membrane (BLM), M Dekker, New York, 1974 Urry, D W, Chemical basis of ion transport specificity in biological membranes, in Topics in Current Chemistry (Ed F L Boschke), Springer-Verlag, Berlin Wilschiit, J, and D.