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When UV light is applied to a vesicular (or micellar) solution for the photoinduced dissociation of the polymer aggregates, it is easy to imagine that the mechanical stirring of the solution may affect the rate of dissociation Besides the change in thermodynamic stability as discussed above, other factors may intervene First, with the copolymer of P(tBA-co-AA)-b-PAzoMA, the membrane of vesicle is formed by a SCLCP bearing azobenzene mesogens, for which the trans cis isomerization could result in a photochemical LC-to-isotropic phase transition that may have an optical plasticization effect on the compact hydrophobic membrane Should this happen, the softened vesicles would become mechanically weaker and thus be more easily broken by the shearing force of the stirring Secondly, under the used low intensity UV light exposed to a large volume of solution (B1.

6

v 2

5 mL), the strong absorption of the chromophore means that it is likely that only azobenzene moieties in the vesicles located nearby the surface of the solution would be excited and undergo the trans cis photoisomerization; the stirring should help the diffusion of polymer vesicles toward the surface region A greater shearing force or/and a faster mixing of the solution at a higher stirring rate should therefore speed the photoinduced dissociation process throughout the solution This indeed is the case Using the same UV irradiation intensity (18 mW cm 2), changes in transmittance of the vesicular solution with no stirring and with stirring at different rates by adjusting the rotation speed of the magnetic bar between about 50 and 300 rmp were recorded and compared in Fig 6.

NH 2 RCOQ-7NH 2 RCOO-

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6a, Note that before the UV irradiation was turned on, the vesicular solution had the same transmittance regardless of the stirring rate, indicating that the shear effect could not break the polymer vesicles It is clear that the process of the vesicle photodissociation became faster as the stirring rate increased Actually, most interesting is the result obtained for the still solution After the UV irradiation was applied on, it showed no change in transmittance.

^H3O+^NH2RCQQ-

At a high level, IB serves as an interconnect for end-nodes. Each end-node can be a processor node, an I/O unit, and/or a router to another network. The IB network is subdivided into subnets that are interconnected by routers. Endnodes can attach to a single subnet or multiple subnets, and a subnet is composed of nodes, switches, routers, and a subnet manager. Each IB device may attach to a single switch or multiple switches and/or directly with each other. Multiple links can exist between any two IB devices.

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Andruzzi L, Altomare A, Ciardelli F, Solaro R, Hvilsted S, Ramanujam PS. 1999. Holographic gratings in azobenzene side chain polymethylmethacrylates. Macromole cules 32:448 454. Barada D, Fukuda T, Itoh M, Yatagai T. 2006. Numerical analysis of photoinduced surface relief formed on azobenzene polymer lm by optical near eld exposure. Jpn J Appl Phys 45:6730 6737. Barret CJ, Natansohn AL, Rochon PL. 1996. Mechanism of optically inscribed high ef ciency diffraction gratings in azo polymer lms. J Phys Chem 100:8836 8842. Batalla E, Natansohn AL, Rochon PL. 1995. Optically induced surface gratings on azoaromatic polymer lms. Appl Phys Lett 66:136 138. Berg RH, Hvilsted S, Ramanujam PS. 1996. Peptide oligomers for holographic data storage. Nature 383:505 508. Betzig E, Trautman JK. 1992. Near eld optics: microscopy, spectroscopy, and surface modi cation beyond the diffraction limit. Science 257:189 219.

KxK2 = aU3O+-

Feng CL, Zhang Z, Forch R, Knoll W, Vancso GJ, Schonherr H 2005 Reactive thin polymer lms as platforms for the immobilization of biomolecules Biomacromolecules 6:3243 3251 Fukuda T, Sumaru K, Kimura T, Matsuda H, Narita Y, Inoue T, Sato F 2001 Observation of optical near eld as photo induced surface relief formation Jpn J Appl Phys 41:L900 L902 Giersig M, Mulvaney P 1993 Preparation of ordered colloid monolayers by electrophore tic deposition Langumuir 9:3408 3413 Hartmann M 2005 Ordered mesoporous materials for bioadsorption and biocatalysis Chem Mater 17:4577 4593 Hasegawa M, Ikawa T, Tsuchimori M, Watanabe O, Kawata Y 2001 Topographical nanostructure patterning on the surface of a thin lm of polyuerthane containing azobenzene moiety using the optical near eld around polystyrene spheres Macro molecules 34:7471 7476 Hasegawa M, Ikawa T, Tsuchimori M, Watanabe O 2002a Photochemically induced birefringence in polyurethanes containing donor acceptor azobenzenes as photorespon sive moieties.

IB is designed around a point-to-point, switched I/O fabric, whereby endnode devices are interconnected by cascaded switched devices. Each node can range from a very inexpensive I/O device (like a single chip SCSI or Ethernet adapter) to very complex host computers. Switched communication allows many devices to communicate concurrently and provides high bandwidth, low latency, and a protected remotely managed environment. End-nodes can communicate over multiple ports and can use multiple paths through the IB fabric. The multiplicity of IB ports and paths through the network is exploited for both fault tolerance and increased data-transfer bandwidth.

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