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Figure 10.2 shows chiral and nonchiral azobenzene compounds. A Ch phase was induced by mixing each chiral azobenzene compound in a host nemaic LC. In such a binary system consisting of a nonchiral host nematic LC and a chiral compound, the reciprocal of the helical pitch (1/p) is known to increase linearly with the concentration (c) of the chiral compound at lower c, and HTP of the chiral compound can be de ned as the slope of the 1/p versus c (Eq. 10.2). Figure 10.3 shows changes in the 1/p of the induced Ch LCs as a function of c in the dark and under ultraviolet (UV) light (365 nm) to cause trans cis photoisomerization of the chiral azobenzene compounds. The helical pitch was determined by Cano s method (Bahr et al., 1991). The 1/p increased almost linearly with the increase of c. HTP of the chiral azobenzenes was on the order of azo-1Wazo-2Wazo-3: 23 102 for azo-1, 6.6 102 for azo-2, and 2.6 102 (mm 1 mol 1 g of E44) for azo-3, respectively (Kurihara et al., 2000). HTP was decreased by increasing the distance between azobenzene group and chiral center. The distance between the azo group and the chiral center is one of the factors in uencing the twisting ability. A decrease in the 1/p was brought about photochemically by UV irradiation. This result means that the trans to cis photoisomerization of these azobenzene compounds caused the decrease in the helical pitch length.

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As more functionality is implemented in IB for blades, more advanced features will become available. For example, it is possible to allocate bandwidth within the HCA to specific virtual lanes. As this feature becomes accessible to virtualization software (see 8, Virtualization ) this will allow for QOS functionality within virtualized environments.

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The distribution of distance h is characterized either by the most probable value hmax, defined by the condition dw(/i)/d/* = 0, or by the mean square of distance h, defined in the usual manner, h2 = $h2w(h) dh/$w(h) dh The ratio (hmax)2/h2 gives the width of the distribution The closer this value is to unity, the narrower the distribution This ratio is equal to \ for the simplest model in statistics, the 'random walk' The problem is then reduced to determining the energy AGfj, which again depends on the model The simplest concept (W Kuhn, A Katchalsky, et al) is to place half of the total charge Q at one end of the polyion and the other half at the other end, from which it follows that AGf,(/i) = Q2/4eh, where e is taken at a first approximation to be the macroscopic permittivity of water.

S811(or R811)

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Another greatly simplified model, corresponding to a certain degree to globular proteins, considers the polyion as a spherically symmetrical charge cloud The electrostatic contribution to the excess Gibbs energy affects the thermodynamic, rheological, transport, and other properties of polyelectrolytes Here, only dissociation equilibria will be considered briefly Consider a molecule of a carboxylic polyacid with degree of polymerization N, bearing N ionizable groups, n of which are actually ionized K'n is the dissociation constant for the ionization of an acidic group bound to an n-times ionized molecule; K^ is the dissociation constant of the group that splits off the first proton and therefore has not yet been affected by the electric field of the other already ionized groups The expression kT\n KQ gives the Gibbs energy change due to ionization of a neutral molecule.

Remote direct memory access (RDMA) is a distributed mechanism that enables a remote processor to access another system s local memory as if it were local memory. Within a single system, direct memory access (DMA) occurs when one application s buffers are placed in a shared memory location that another application can access through DMA. As shown in Figure 6.7, the local process includes a local copy mechanism where information is copied into memory and a DMA engine can then copy that information from the source address to a destination address in another application s memory space. In a traditional technology such as Ethernet or Fibre Channel, when the adapter card is signaled via I/O interrupt to begin processing a request for movement, it reaches into local memory through the DMA process. This process makes it unnecessary to interrupt the CPU until that transfer is complete. As shown in Figure 6.8, the RDMA process is designed to transfer information from the memory space of one computer (src address) to the memory space of another (dst address), regardless of size and location. Additionally, no intermediate I/O interrupts are required on long and large transfers until the entire operation is completed, freeing up CPU cycles on both systems.

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