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So far photoinduced or phototriggered mass migrations (see Section 8.4) have been achieved for homopolymers or random copolymers. Quite recently, block copolymers have also been subjected to mass migration (Morikawa et al., 2006; Fig. 8.20). The key for the out-of-plane alignment (whether the cylinders orient normal or parallel to the substrate surface) is the control of lm thickness and that for the in-plane control is the adjustment of direction of LPL. This polymer adopts hexagonally packed PEO cylinders orienting normal to the substrate plane over long distance ranges in thin lm because of its liquid crystallinity (Tian et al., 2002). However, the nanocylinders orient parallel to the substrate plane when the thickness becomes o70 nm (Morikawa et al., 2006, Watanabe et al., 2006). For other systems, thickness change of a polymer lm o100 nm is found to alter the nanostructures and their orientations for block copolymer systems (Knoll et al., 2002) and also in uence the orientation of mesogenic groups with respect to the

Reinhold, New York, 1950. Robinson, R. A., and R. H. Stokes, Electrolyte Solutions, Butterworths, London, 1959.

(p- : p-)

4

1.4 Acids and Bases The Arrhenius concept was of basic importance because it permitted quantitative treatment of a number of acid-base processes in aqueous solutions, i.e. the behaviour of acids, bases, their salts and mixtures of these substances in aqueous solutions. Nonetheless, when more experimental material was collected, particularly on reaction rates of acid-base catalysed processes, an increasing number of facts was found that was not clearly interpretable on the basis of the Arrhenius theory (e.g. in anhydrous acetone NH3 reacts with acids in the absence of OH~ and without the formation of water). It gradually became clear that a more general theory was needed. Such a theory was developed in 1923 by J. N. Br0nsted and, independently, by T. M. Lowry. 1.4.1 Definitions The generalization was based on the introduction of the concept of donor-acceptor pairs into the theory of acids and bases; this is a fundamental concept in the general interpretation of chemical reactivity. In the same way as a redox reaction depends on the exchange of electrons between the two species forming the redox system, reactions in an acid-base system also depend on the exchange of a chemically simple species hydrogen cations, i.e. protons. Such a reaction is thus termed protolytic. This approach leads to the following definitions: An acid HA is a substance capable of splitting off a proton: A base B is a substance capable of bonding a proton: B + H + ->BH + Substances capable of splitting off a proton, i.e. proton donors, are termed protogenic and, on the other hand, substances accepting protons, i.e. proton

(s- : s-)

46 accceptors, are protophilic Some substances can exhibit both of these properties, ie can either accept or donate a proton, and are termed amphiprotic The pairs HA A and B HB differ only by the presence or absence of a proton (in the same way as the oxidized form differs from the reduced form in a redox system only by the presence or absence of an electron) The substances HA and A~ or B and BH + form a conjugate pair A strong acid is conjugate with a weak base and a strong base is conjugate with a weak acid An important characteristic of the definitions should be noted: no mention is made of the charge of species HA, A, B and HB Acids and bases can be either electrically neutral molecules or ions.

As can be seen in the figures, the front of the chassis has blades that can be inserted and removed, and the rear of the chassis houses the fans, the power supplies, the shared switch modules, and the management module. The blade chassis is generally designed to allow the blades to be inserted from the front, and the switch modules to be inserted from the back, connected by a midplane. Because previous chassis architectures inserted everything from the front and all of the power distribution and connection functions were implemented on the back, these functions have traditionally been known as the backplane. In blade server systems, however, the backplane function often is implemented through the midplane. Figure 4.5 shows an example of an open chassis. In the middle of the chassis is the passive midplane, providing the power-distribution line to each component, as well as the connectivity between all of the blade system components. The midplane typically has connectors on both sides that provide the connectivity to each of the components in the blade system.

Figure 8.21. Schematic illustration of hierarchical structures involved in photogenerated SRG of a block copolymer after irradiation with (p- : p-) and (s- : s-) mode interference laser beam. Note that the in-plane direction of the cylinder is clearly controlled by the polarization mode. The out-of-plane change is because of the thickness variation. See color insert.