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471 obtained in the oxidation of the carbonaceous substrate accumulates in the form of a single 'macroenergetic' compound of ATP, two energy-rich compounds are formed during photosynthesis, NADPH2 and ATP, both of which are consumed in the synthesis of sugars The subsequent steps appear to be purely biochemical in character and therefore will not be considered here In a partly biological, partly artificial model (page 397) reduced anthraquinone-2-sulphonate plays the role of NAD + and tetramethyl-/ phenylenediamine that of plastoquinones References Baker, P F (Ed), The Squid Axon Current Topics in Membranes and Transport, Vol 22, Academic Press, Orlando, 1984 Barber, J (Ed), Topics in Photosynthesis, Vols 1-3, Elsevier, Amsterdam, 1978 Briggs, W R (Ed), Photosynthesis, A R Liss, New York, 1990 Calahan, M, Molecular properties of sodium channels in excitable membranes, in The Cell Surface and Neuronal Function (Eds C W Cotman, G.

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Figure 8.18. Structure of Az-containing LC block copolymers employed for photocontrol of MPS nanocylinders.

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Poste and G L Nicholson), P I, Elsevier, Amsterdam, 1980 Catteral, W A, The molecular basis of neuronal excitability, Science, 223, 653 (1984) Cole, K S, Membranes, Ions and Impulses, University of California Press, Berkeley, 1968 Conti, F, and E Neher, Single channel recordings of K+ currents in squid axons, Nature, 285, 140 (1980) Cramer, W A, and D B Knaff, Energy Transduction in Biological Membranes, A Textbook of Bioenergetics, Springer-Verlag, Berlin, 1989 French, R J, and R Horn, Sodium channel gating: models, mimics and modifiers, Ann Rev Biophys Bioeng, 12, 319 (1983) Govindjee (Ed), Photosynthesis, Vols 1 and 2, Academic Press, New York, 1982 Hagiwara, S, and L Byerly, Calcium channel, Ann Rev Neurosci, 4, 69 (1981) Hille, B, Ionic Channels of Excitable Membranes, Sinauer, Sunderland, 1984 Katz, B, Nerve, Muscle and Synapse, McGraw-Hill, New York, 1966.

LPL 130 30 C Non LPL 130 30 C Annealing Annealing LPL 0.6 LPL Az 0.4 LPL Az LPL 0.6 0.4 LPL Az LPL // Az 0.2 0.2 LPL // Az 320 420 520 Wavelength/nm (b) 620 0 220 320 420 520 Wavelength/nm (c) 620 0 220 320 420 520 Wavelength/nm (d)

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Keynes, R D, The generation of electricity by fishes, Endeavour, 15, 215 (1956) Keynes, R D, Excitable membranes, Nature, 239, 29 (1972) Lee, C P, G Schatz, and L Ernster (Eds), Membrane Bioenergetics, AddisonWesley, Reading, Mass, 1979 Mitchell, P, Davy's electrochemistry Nature's protochemistry, Chemistry in Britain, 17, 14 (1981) Mitchell, P, Keilin's respiratory chain concept and its chemiosmotic consequences, Science, 206, 1148 (1979) Moore, J W (Ed), Membranes, Ions and Impulses, Plenum Press, 1976 Nicholls, D G, Bioenergetics, An Introduction to the Chemiosmotic Theory, Academic Press, Orlando, 1982 Sakmann, B, and E Neher (Eds), Single-Channel Recordings, Plenum Press, New York, 1983 Sauer, K, Photosynthetic membranes, Ace Chem Res, 11, 257 (1978) Skulatchev, V P, Membrane bioenergetics Should we build the bridge across the river or alongside of it , Trends Biochem Sci, 9, 182 (1984) Stein, W.

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D (Ed), Current Topics in Membranes and Transport, Vol 21, Ion Channels: Molecular and Physiological Aspects, Academic Press, Orlando, 1984..

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Stevens, C. F., Biophysical studies in channels, Science, 225, 1346 (1984). Stroud, R. M., and J. Tinner-Moore, Acetylcholine receptor, structure, formation and evolution, Ann. Rev. Cell BioL, 1, 317 (1985). Tsien, R. W., Calcium channels in excitable cell membranes, Ann. Rev. Physiol., 45, 341 (1983). Ulbricht, W., Ionic channels and gating currents in excitable membranes, Ann. Rev. Biophys. Bioeng., 6, 7 (1977). Urry, D. W., A molecular theory of ion-conducting channels: A field dependent transition between conducting and non-conducting conformations, Proc. Natl. Acad. Sci. USA, 69, 1610 (1972). Van Dam, K., and B. F. Van Gelder (Eds.), Structure and Function of Energy Transducing Membranes, Elsevier, Amsterdam, 1977. Witt, H. T., Charge separation in photosynthesis, Light-Induced Charge Separation in Biology and Chemistry (ed. H. Gerischer and J. J. Katz), Verlag Chemie, Weinheim, 1979.

Robinson and Stokes have demonstrated that, for simplifying assumptions, the following relationship is valid between ar's and )3's: (a,+ a II ) = fc-2rn(i8I + i8II) (1.3.49) where A is a constant independent of the molality. : A particular case of electrolyte mixtures occurs if one electrolyte is present in a large excess over the others, thus determining the value of the ionic strength. In this case the ionic atmospheres of all the ions are formed almost exclusively from these excess ions. Under these conditions, the activities of all the ions present in the solution are proportional to their concentrations, the activity coefficient being a function of the concentration of the excess electrolyte alone. The excess electrolyte is often termed the indifferent electrolyte. From the practical point of view, solutions containing an indifferent electrolyte are very often used in miscellaneous investigations. For example, when determining equilibrium constants (e.g. apparent dissociation constants, Eq. 1.1.26) it is necessary only to indicate the indifferent electrolyte and its concentration, as they do not change when the concentrations of the reactants are changed. Moreover, the indifferent electrolyte is important in the study of diffusion transport (Section 2.5), for elimination of liquid

0 220

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